NMR assignment of absolute configuration of a P-chiral diphosphine and mechanics of its stereoselective formation

Two-dimensional rotating-frame nuclear Overhauser enhancement (ROESY) NMR spectra are used to determine the absolute configuration of (+)-diphenyl- phosphine-2,3-dimethyl-7-phenyl-7-phosphabicyclo[2.2.1]hept-2-ene. This diphosphine ligand is obtained from the palladium complex-promoted Diels- Alder...

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Main Authors: Aw, B, Selvaratnam, S, Leung, P, Rees, N, McFarlane, W
格式: Journal article
语言:English
出版: 1996