Dynamics of excited-state conformational relaxation and electronic delocalization in conjugated porphyrin oligomers.

We have investigated the influence of nuclear geometric relaxation on the extent of the excited-state electronic delocalization in conjugated zinc porphyrin oligomers using ultrafast transient photoluminescence spectroscopy. By use of metal-coordinating templates that force the oligomers into specif...

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Bibliographic Details
Main Authors: Chang, M, Hoffmann, M, Anderson, H, Herz, L
Format: Journal article
Language:English
Published: 2008