Widening the usefulness of epoxides and aziridines in synthesis

Deprotonation of terminal epoxides and aziridines with organolithium/ diamine combinations or lithium amides allows the regio- and stereoselective formation of α-lithiated species. Judicious choice of reaction conditions allows these species to operate as nucleophiles, enolate equivalents, vinyl cat...

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Autors principals: Hodgson, D, Humphreys, P, Hughes, S
Format: Journal article
Idioma:English
Publicat: 2007