Widening the usefulness of epoxides and aziridines in synthesis
Deprotonation of terminal epoxides and aziridines with organolithium/ diamine combinations or lithium amides allows the regio- and stereoselective formation of α-lithiated species. Judicious choice of reaction conditions allows these species to operate as nucleophiles, enolate equivalents, vinyl cat...
| Main Authors: | , , |
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| Format: | Journal article |
| Language: | English |
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2007
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| _version_ | 1797053699535667200 |
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| author | Hodgson, D Humphreys, P Hughes, S |
| author_facet | Hodgson, D Humphreys, P Hughes, S |
| author_sort | Hodgson, D |
| collection | OXFORD |
| description | Deprotonation of terminal epoxides and aziridines with organolithium/ diamine combinations or lithium amides allows the regio- and stereoselective formation of α-lithiated species. Judicious choice of reaction conditions allows these species to operate as nucleophiles, enolate equivalents, vinyl cation equivalents, or carbenes. © 2007 IUPAC. |
| first_indexed | 2024-03-06T18:47:20Z |
| format | Journal article |
| id | oxford-uuid:0ef433b2-3b53-497b-8e8b-4d84af3dd111 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-06T18:47:20Z |
| publishDate | 2007 |
| record_format | dspace |
| spelling | oxford-uuid:0ef433b2-3b53-497b-8e8b-4d84af3dd1112022-03-26T09:48:51ZWidening the usefulness of epoxides and aziridines in synthesisJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:0ef433b2-3b53-497b-8e8b-4d84af3dd111EnglishSymplectic Elements at Oxford2007Hodgson, DHumphreys, PHughes, SDeprotonation of terminal epoxides and aziridines with organolithium/ diamine combinations or lithium amides allows the regio- and stereoselective formation of α-lithiated species. Judicious choice of reaction conditions allows these species to operate as nucleophiles, enolate equivalents, vinyl cation equivalents, or carbenes. © 2007 IUPAC. |
| spellingShingle | Hodgson, D Humphreys, P Hughes, S Widening the usefulness of epoxides and aziridines in synthesis |
| title | Widening the usefulness of epoxides and aziridines in synthesis |
| title_full | Widening the usefulness of epoxides and aziridines in synthesis |
| title_fullStr | Widening the usefulness of epoxides and aziridines in synthesis |
| title_full_unstemmed | Widening the usefulness of epoxides and aziridines in synthesis |
| title_short | Widening the usefulness of epoxides and aziridines in synthesis |
| title_sort | widening the usefulness of epoxides and aziridines in synthesis |
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