Fe-catalyzed conversion of N2 to N(SiMe3)3 via an Fe-hydrazido resting state
The catalytic conversion of N2 to N(SiMe3)3 by homogenous transition metal compounds is a rapidly developing field, yet few mechanistic details have been experimentally elucidated for 3d element catalysts. Herein we show that Fe(PP)2(N2) (PP = R2PCH2CH2PR2; R = Me, 1Me; R = Et, 1Et) are highly effec...
| Main Authors: | , , , , |
|---|---|
| Format: | Journal article |
| Language: | English |
| Published: |
American Chemical Society
2018
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