Fe=B double bonds: Synthetic, structural, and reaction chemistry of cationic terminal borylene complexes

Application of halide abstraction chemistry to asymmetric haloboryl complexes (η5-C5-Me5)Fe(CO) 2B(ERn)X leads to the first synthetic route to cationic multiply bonded group 13 diyl species, [(η5-C5Me 5)Fe(CO)2B(ERn]+. The roles of steric bulk and π electron release within the ERn substituent in gen...

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Bibliographic Details
Main Authors: Coombs, D, Aldridge, S, Rossin, A, Jones, C, Willock, D
Format: Journal article
Language:English
Published: 2004