Homologous critical behavior in the molecular frameworks Zn(CN)(2) and Cd(imidazolate)(2)

Using a combination of single-crystal and powder X-ray diffraction measurements, we study temperature- and pressure-driven structural distortions in zinc(II) cyanide (Zn(CN)₂) and cadmium(II) imidazolate (Cd(im)₂), two molecular frameworks with the anticuprite topology. Under a hydrostatic pressure...

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Bibliographic Details
Main Authors: Collings, I, Cairns, A, Thompson, A, Parker, J, Tang, C, Tucker, M, Catafesta, J, Levelut, C, Haines, J, Dmitriev, V, Pattison, P, Goodwin, A
Format: Journal article
Language:English
Published: American Chemical Society 2013
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