Homologous critical behavior in the molecular frameworks Zn(CN)(2) and Cd(imidazolate)(2)
Using a combination of single-crystal and powder X-ray diffraction measurements, we study temperature- and pressure-driven structural distortions in zinc(II) cyanide (Zn(CN)₂) and cadmium(II) imidazolate (Cd(im)₂), two molecular frameworks with the anticuprite topology. Under a hydrostatic pressure...
Main Authors: | , , , , , , , , , , , |
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Format: | Journal article |
Language: | English |
Published: |
American Chemical Society
2013
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Subjects: |