Extension of hydrogen borrowing alkylation reactions for the total synthesis of (–)-γ-lycorane
The total synthesis of (–)-γ-lycorane (10 steps) and synthesis of (±)-
γ-lycorane (8 steps) was completed from cyclohexenone. A new
two step hydrogen borrowing alkylation of an aziridinyl alcohol,
coupled with a Ph* deprotection/cyclisation procedure was
developed for de novo formation of the fused...
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Bibliographic Details
| Main Authors: |
Hall, C,
Marriott, I,
Christensen, K,
Day, A,
Goundry, W,
Donohoe, TJ |
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| Format: | Journal article
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| Language: | English |
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| Published: |
Royal Society of Chemistry
2022
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