Atmospheric chemistry of CF3CH2OCHF2 and CF3CHClOCHF2: Kinetics and mechanisms of reaction with Cl atoms and OH radicals and atmospheric fate of CF3C(O center dot)HOCHF2 and CF3C(O center dot)ClOCHF2 radicals

Atmospheric chemistry of CF3CH2OCHF2 and CF3CHClOCHF2: Kinetics and mechanisms of reaction with Cl atoms and OH radicals and atmospheric fate of CF3C(O center dot)HOCHF2 and CF3C(O center dot)ClOCHF2 radicals

Relative rate techniques were used to measure k(Cl + CF3CH2OCHF2) = (1.2 ± 0.1) × 10-14, k(Cl + CF3CHClOCHF2) = (5.4 ± 0.5) × 10-15, k(Cl + HC(O)OCHF2) = (2.0 ± 0.2) × 10-14, and k(Cl + CF3C(O)OCHF2) < 4 × 10-17 cm3 molecule-1 s-1 at 295 K. Cl atoms react with CF3CHClOCHF2 (isoflurane, HCFE-2...

书目详细资料
Main Authors:	Wallington, T, Hurley, MD, Fedotov, V, Morrell, C, Hancock, G
格式:	Journal article
语言:	English
出版:	2002

相似书籍

Computer-simulated degradation of CF3Cl, CF2Cl2, and CFCl3 under electron beam irradiation
由: Kabasa Stephen, et al.
出版: (2023-07-01)

Diversity-oriented approach to CF3CHF-, CF3CFBr-, CF3CF2-, (CF3)2CH-, and CF3(SCF3)CH-substituted arenes from 1-(diazo-2,2,2-trifluoroethyl)arenes.
由: Emer, E, et al.
出版: (2014)

LASER-INDUCED FLUORESCENCE DETECTION OF CF AND CF2 RADICALS IN A CF4/O2 PLASMA
由: Booth, J, et al.
出版: (1987)

CF3SO2X (X = Na, Cl) as reagents for trifluoromethylation, trifluoromethylsulfenyl-, -sulfinyl- and -sulfonylation and chlorination. Part 2: Use of CF3SO2Cl
由: Hélène Chachignon, et al.
出版: (2017-12-01)

SPATIALLY AND TEMPORALLY RESOLVED LASER-INDUCED FLUORESCENCE MEASUREMENTS OF CF2 AND CF RADICALS IN A CF4 RF PLASMA
由: Booth, J, et al.
出版: (1989)

Why •CF2H is nucleophilic but •CF3 is electrophilic in reactions with heterocycles
由: Meng Duan, et al.
出版: (2024-05-01)

Tropospheric photooxidation of CF<sub>3</sub>CH<sub>2</sub>CHO and CF<sub>3</sub>(CH<sub>2</sub>)<sub>2</sub>CHO initiated by Cl atoms and OH radicals
由: J. Albaladejo, et al.
出版: (2010-02-01)

CF3SO2X (X = Na, Cl) as reagents for trifluoromethylation, trifluoromethylsulfenyl-, -sulfinyl- and -sulfonylation. Part 1: Use of CF3SO2Na
由: Hélène Guyon, et al.
出版: (2017-12-01)

Copper-Mediated −CF(OCF3)(CF2H) Transfer to Organic Electrophiles
由: Behnaz Ghaffari, et al.
出版: (2024-09-01)

Measurement report: Radiative efficiencies of (CF<sub>3</sub>)<sub>2</sub>CFCN, CF<sub>3</sub>OCFCF<sub>2</sub>, and CF<sub>3</sub>OCF<sub>2</sub>CF<sub>3</sub>
由: B. A. Trisna, et al.
出版: (2023-04-01)

The [3+2] Annulation of CF3-Ketimines by Re Catalysis: Access to CF3-Containing Amino Heterocycles and Polyamides
由: Saisai Zhang, et al.
出版: (2020-11-01)

Infrared emission from the CF3+NO2 reaction
由: Oum, K, et al.
出版: (1997)

The synthesis and characterisation of some Group 14 compounds containing the 2,4,6-(CF3)(3)C6H2, 2,6-(CF3)(2)C6H3 or 2,4-(CF3)(2)C6H3 ligands
由: Batsanov, A, et al.
出版: (2003)

Redox chemistry of trifluoromethyl sulfonium salts as CF3 radical sources
由: Mizuta, S, et al.
出版: (2013)

PhI(OAc)2 mediated radical trifluoromethylation of vinyl azides with Me3SiCF3
由: Wang, Yi-Feng, et al.
出版: (2014)

Study of MgO transformation into MgF2 in the presence of CF2Cl2•
由: Vedyagin Aleksey A., et al.
出版: (2017-01-01)

Effects of hydrophobic chain structure on adsorption of fluorocarbon surfactants with either CF3- or H-CF2-terminal groups
由: Downer, A, et al.
出版: (1999)

An Efficient Synthesis of 2-CF<sub>3</sub>-3-Benzylindoles
由: Vasiliy M. Muzalevskiy, et al.
出版: (2021-08-01)

New group 15 compounds containing the 2,4,6-(CF3)(3)C6H2(fluoromes = Ar), 2,6-(CF3)(2)C6H3 (fluoroxyl = Ar ') or 2,4-(CF3)(2)C6H3 (Ar '') ligands
由: Batsanov, A, et al.
出版: (2002)

Synthesis and characterisation of some new boron compounds containing the 2,4,6-(CF3)(3)C6H2 (fluoromes = Ar), 2,6-(CF3)(2)C6H3 (fluoroxyl = Ar '), or 2,4-(CF3)(2)C6H3 (Ar '') ligands
由: Cornet, S, et al.
出版: (2003)

SERCA2 regulates non-CF and CF airway epithelial cell response to ozone.
由: Shama Ahmad, et al.
出版: (2011-01-01)

Fluorinated nonionic surfactants bearing either CF3- or H-CF2- terminal groups: Adsorption at the surface of aqueous solutions
由: Eastoe, J, et al.
出版: (2001)

Ionic Association in CH3–(CH2–CF2)n–CH3(PVDF)–Li+–(CF3SO2)2N– for n = 1, 4: A Computational Approach
由: Mathew Daniel, et al.
出版: (2022-02-01)

Atmospheric chemistry of trans-CF3CH=CHF: products and mechanisms of hydroxyl radical and chlorine atom initiated oxidation
由: T. J. Wallington, et al.
出版: (2008-06-01)

Synthesis and Reactions of 3-Halogenated 2-CF<sub>3</sub>-Indoles
由: Vasiliy M. Muzalevskiy, et al.
出版: (2022-12-01)

THE STRUCTURE OF SOLID CF3I
由: Clarke, S, et al.
出版: (1993)

Deuteriodifluoromethylation and gem‐Difluoroalkenylation of Aldehydes Using ClCF2H in Continuous Flow
由: Fu, Wai Chung, et al.
出版: (2020)

CfA3: 185 TYPE Ia SUPERNOVA LIGHT CURVES FROM THE CfA
由: Krauss, Miriam, et al.
出版: (2015)

Synthesis and Reactivity of Mn–CF3 Complexes
由: Alex L. Daniels, et al.
出版: (2019-01-01)

Pathogenesis, imaging and clinical characteristics of CF and non-CF bronchiectasis
由: Schäfer, Jürgen, et al.
出版: (2018)

Pathogenesis, imaging and clinical characteristics of CF and non-CF bronchiectasis
由: Jürgen Schäfer, et al.
出版: (2018-05-01)

THE RADIATIVE LIFETIME OF CF(A2SIGMA+)
由: Booth, J, et al.
出版: (1988)

BrCF2CN for photocatalytic cyanodifluoromethylation
由: Xin-Jun Yang, et al.
出版: (2025-01-01)

Study on suppression of CH4 explosion by CF3H and CO2
由: Jieqi BAI, et al.
出版: (2024-05-01)

The difluoromethylene (CF2) group in aliphatic chains: Synthesis and conformational preference of palmitic acids and nonadecane containing CF2 groups
由: Yi Wang, et al.
出版: (2014-01-01)

CF2H-synthon enables asymmetric radical difluoroalkylation for synthesis of chiral difluoromethylated amines
由: Peng Liu, et al.
出版: (2025-01-01)

The Metamorphosis of Mg(SO3CF3)2‐based Electrolytes for Rechargeable Magnesium Batteries
由: Dr. Jinlong Chen, et al.
出版: (2024-04-01)

Geological hazard susceptibility evaluation based on CF and CF-LR model
由: Shuiyun TU, et al.
出版: (2022-04-01)

Impact of vitamin D status on CF and non-CF bronchiectasis outcomes
由: Heba A. Ali, et al.
出版: (2022-01-01)

CF 2000 ECUMÊNICA: EPISÓDIO OU NOVA FASE DA CF?
由: Gabriele Cipriani
出版: (2001-01-01)