SOME SUBSTITUTION-REACTIONS OF LIGANDS COORDINATED TO THE BIS(CYCLOPENTADIENYL)TITANIUM MOIETY, THE X-RAY CRYSTAL-STRUCTURE OF TI(ETA-5-C5H5)2(OPH)2 AND AN ASSESSMENT OF THE ANTITUMOR-ACTIVITY OF SOME CYCLOPENTADIENYL TITANIUM COMPOUNDS

The new complexes Ti(η5-C5H5)Cl(OC6H4NH2-3)2, Ti(η5-C5H5)Cl(O2CPh)2, Ti(η5-C5H5)2(O2C(S)C6H4-1,2), Ti(η5-C5H5)2Cl(SC6H4OH-4), Ti(η5-C5H5)2(OC6H4NH2-3)2 and Ti(η5-C5H5)2Cl(OC6H4Z) (Z = NO2-2, NO2-3, NO2-4, NH2-3) have been synthesized. The free amine group in Ti(η5-C5H5)2Cl(OC6H4NH2-3) reacts with RC...

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Bibliographic Details
Main Authors: Kalirai, B, Foulon, J, Hamor, T, Jones, C, Beer, P, Fricker, S
Format: Journal article
Published: 1991