Cationic terminal borylene complexes: a synthetic and mechanistic investigation of M=B metathesis chemistry.
(Chemical Equation Presented) Halide abstraction chemistry has been exploited to generate the cationic terminal borylene complex 1, which reacts with Ph3P=S or Ph3As=O to form 3 and 4. In the case of the corresponding reaction with Ph3P=O, the intermediate 2 can be isolated, which provides evidence...
| Main Authors: | , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
2005
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