Cationic terminal borylene complexes: a synthetic and mechanistic investigation of M=B metathesis chemistry.
(Chemical Equation Presented) Halide abstraction chemistry has been exploited to generate the cationic terminal borylene complex 1, which reacts with Ph3P=S or Ph3As=O to form 3 and 4. In the case of the corresponding reaction with Ph3P=O, the intermediate 2 can be isolated, which provides evidence...
| Main Authors: | , , , |
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| Format: | Journal article |
| Language: | English |
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2005
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| _version_ | 1797054479577645056 |
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| author | Kays, D Day, J Ooi, L Aldridge, S |
| author_facet | Kays, D Day, J Ooi, L Aldridge, S |
| author_sort | Kays, D |
| collection | OXFORD |
| description | (Chemical Equation Presented) Halide abstraction chemistry has been exploited to generate the cationic terminal borylene complex 1, which reacts with Ph3P=S or Ph3As=O to form 3 and 4. In the case of the corresponding reaction with Ph3P=O, the intermediate 2 can be isolated, which provides evidence for a two-step addition/substitution mechanism for the overall metathesis reaction. © 2005 Wiley-VCH Verlag GmbH and Co. KGaA. |
| first_indexed | 2024-03-06T18:57:49Z |
| format | Journal article |
| id | oxford-uuid:1274022a-fc9f-4ec6-82c9-475e65369e08 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-06T18:57:49Z |
| publishDate | 2005 |
| record_format | dspace |
| spelling | oxford-uuid:1274022a-fc9f-4ec6-82c9-475e65369e082022-03-26T10:08:04ZCationic terminal borylene complexes: a synthetic and mechanistic investigation of M=B metathesis chemistry.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:1274022a-fc9f-4ec6-82c9-475e65369e08EnglishSymplectic Elements at Oxford2005Kays, DDay, JOoi, LAldridge, S(Chemical Equation Presented) Halide abstraction chemistry has been exploited to generate the cationic terminal borylene complex 1, which reacts with Ph3P=S or Ph3As=O to form 3 and 4. In the case of the corresponding reaction with Ph3P=O, the intermediate 2 can be isolated, which provides evidence for a two-step addition/substitution mechanism for the overall metathesis reaction. © 2005 Wiley-VCH Verlag GmbH and Co. KGaA. |
| spellingShingle | Kays, D Day, J Ooi, L Aldridge, S Cationic terminal borylene complexes: a synthetic and mechanistic investigation of M=B metathesis chemistry. |
| title | Cationic terminal borylene complexes: a synthetic and mechanistic investigation of M=B metathesis chemistry. |
| title_full | Cationic terminal borylene complexes: a synthetic and mechanistic investigation of M=B metathesis chemistry. |
| title_fullStr | Cationic terminal borylene complexes: a synthetic and mechanistic investigation of M=B metathesis chemistry. |
| title_full_unstemmed | Cationic terminal borylene complexes: a synthetic and mechanistic investigation of M=B metathesis chemistry. |
| title_short | Cationic terminal borylene complexes: a synthetic and mechanistic investigation of M=B metathesis chemistry. |
| title_sort | cationic terminal borylene complexes a synthetic and mechanistic investigation of m b metathesis chemistry |
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