A three-state model for the polymorphism in linear tricobalt compounds.

The remarkable polymorphism exhibited by the linear tricobalt compounds, Co3(mu3-dpa)4Cl2 and Co3(mu3-dpa)4Br2, can be explained using a model involving three distinct electronic states. At high temperatures, symmetric and unsymmetric forms arise from the population of doublet (2A) and quartet (4B)...

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Bibliographic Details
Main Authors: Pantazis, D, McGrady, J
Format: Journal article
Language:English
Published: 2006