Comparative evaluation of the symmetric and asymmetric Marcus-Hush formalisms of electrode kinetics - The one-electron oxidation of tetraphenylethylene in dichloromethane on platinum microdisk electrodes
We report an experimental comparative evaluation of the Butler-Volmer (BV), symmetric and asymmetric Marcus-Hush (MH) kinetic formalisms. Numerical simulations using these kinetic models are employed to fit experimental cyclic voltammetry of the one-electron oxidation of tetraphenylethylene in dichl...
| Main Authors: | , , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
2012
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