Syntheses and Structural Diversity of Group 2 and Group 12 Tris(pyrazolyl)methane and Zwitterionic Tris(pyrazolyl)methanide Compounds
Reaction of HC(Me2pz)3 with Mg(N(SiMe 3)2}2 gave the zwitterionic amide complex Mg{C(Me2pz)3}{N(SiMe3)2} (13), containing a "free" pyramidal carbanion and a cationic {Mg-N(SiMe 3)2}+ moiety. Reaction of the less bulky amide Mg{N(SiHMe2)2}2 with RC(Me2pz) 3 (R = H or D) gave the four-coordi...
| Главные авторы: | , , , , , , |
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| Формат: | Journal article |
| Язык: | English |
| Опубликовано: |
2010
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