Negative area compressibility in silver(I) tricyanomethanide.

The molecular framework Ag(tcm) (tcm(-) = tricyanomethanide) expands continuously in two orthogonal directions under hydrostatic compression. The first of its kind, this negative area compressibility behaviour arises from the flattening of honeycomb-like layers during rapid pressure-driven collapse...

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Bibliographic Details
Main Authors: Hodgson, SA, Adamson, J, Hunt, S, Cliffe, M, Cairns, AB, Thompson, A, Tucker, MG, Funnell, N, Goodwin, A
Format: Journal article
Language:English
Published: Royal Society of Chemistry 2014