Anomeric oxygen to carbon rearrangements of alkynyl tributylstannane derivatives of lactols.

Treatment of alkynyl tributylstannane tetrahydropyranyl and tetrahydrofuranyl ether derivatives with boron trifluoride etherate effects an efficient anomeric oxygen to carbon rearrangement leading to the corresponding carbon-linked alkynol products.

Библиографические подробности
Главные авторы: Buffet, M, Dixon, D, Ley, S, Tate, E
Формат: Journal article
Язык:English
Опубликовано: 1998
Описание
Итог:Treatment of alkynyl tributylstannane tetrahydropyranyl and tetrahydrofuranyl ether derivatives with boron trifluoride etherate effects an efficient anomeric oxygen to carbon rearrangement leading to the corresponding carbon-linked alkynol products.