Anomeric oxygen to carbon rearrangements of alkynyl tributylstannane derivatives of lactols.
Treatment of alkynyl tributylstannane tetrahydropyranyl and tetrahydrofuranyl ether derivatives with boron trifluoride etherate effects an efficient anomeric oxygen to carbon rearrangement leading to the corresponding carbon-linked alkynol products.
Principais autores: | Buffet, M, Dixon, D, Ley, S, Tate, E |
---|---|
Formato: | Journal article |
Idioma: | English |
Publicado em: |
1998
|
Registros relacionados
-
Anomeric oxygen to carbon rearrangements of alkynyl tributylstannane derivatives of furanyl (gamma)- and pyranyl (delta)-lactols.
por: Buffet, M, et al.
Publicado em: (2004) -
Diastereoselective anomeric oxygen to carbon rearrangements of silyl enol ether derivatives of lactols.
por: Dixon, D, et al.
Publicado em: (1998) -
A general C-glycosidation procedure via anomeric oxygen to carbon rearrangements of tetrahydropyranyl ether derivatives
por: Buffet, M, et al.
Publicado em: (1997) -
A total synthesis of (+)-Goniodiol using an anomeric oxygen-to-carbon rearrangement
por: Dixon, D, et al.
Publicado em: (1998) -
Oxygen to carbon rearrangements of anomerically linked alkenols from tetrahydropyran derivatives: an investigation of the reaction mechanism via a double isotopic labelling crossover study
por: Buffet, M, et al.
Publicado em: (2000)