Activation of H-2 by halogenocarbonylbis(phosphine)rhodium(I) complexes. The use of parahydrogen induced polarisation to detect species present at low concentration
Complexes of the form RhX(CO)(PR3)2 [X = Cl, Br or I; R = Me or Ph] reacted with H2 to form a series of binuclear complexes of the type (PR3)2H2Rh(μ-X)2Rh(CO)(PR 3) [X = Cl, Br or I, R = Ph; X = I, R = Me] and (PMe3)2(X)HRh(μ-H)(μ-X)Rh(CO)(PMe3) [X = Cl, Br or I] according to parahydrogen sensitised...
| Main Authors: | , , , , , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
1999
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