Synthesis and properties of [CoCp*(2,5-PC4tBu2H2)]: the first monophosphacobaltocene.
The reduction of the phosphacobaltocenium salt [CoCp*(2,5-PC(4)tBu(2)H(2))](+)[BPh(4)](-) (3; Cp*=pentamethylcyclopentadienyl) by magnesium in tetrahydrofuran (THF) furnishes the stable air-sensitive phosphacobaltocene [CoCp*(2,5-PC(4)tBu(2)H(2))] (4) in yields of up to 80 %. The crystal structure o...
| Main Authors: | , , , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
2003
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