Changing the local coordination environment in mono- and bi- nuclear lanthanide complexes through "click" chemistry.

Alkyne appended lanthanide complexes derived from DO3A undergo copper catalysed cycloaddition reactions with azides to form triazole appended complexes: coordination of one of the triazole nitrogen atoms to the metal centre changes the local coordination environment and the spectroscopic properties...

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Detalles Bibliográficos
Autores principales: Jauregui, M, Perry, W, Allain, C, Vidler, L, Willis, M, Kenwright, A, Snaith, J, Stasiuk, G, Lowe, M, Faulkner, S
Formato: Journal article
Lenguaje:English
Publicado: 2009
Descripción
Sumario:Alkyne appended lanthanide complexes derived from DO3A undergo copper catalysed cycloaddition reactions with azides to form triazole appended complexes: coordination of one of the triazole nitrogen atoms to the metal centre changes the local coordination environment and the spectroscopic properties of the complex.