Direct observation of the ultrafast intersystem crossing in tris(2,2 '-bipyridine) ruthenium(II) using femtosecond stimulated Raman spectroscopy
Time-resolved femtosecond stimulated Raman spectroscopy (FSRS) is used to explore the ultrafast intersystem crossing between the metal-to-ligand charge-transfer (MLCT) states of tris(2,2'-bipyridine)ruthenium(II) (). Excitation at 480?nm by a ~35?fs actinic pump pulse initiates electron transfe...
| Главные авторы: | , , , |
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| Формат: | Journal article |
| Язык: | English |
| Опубликовано: |
2006
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