Direct observation of the ultrafast intersystem crossing in tris(2,2 '-bipyridine) ruthenium(II) using femtosecond stimulated Raman spectroscopy
Time-resolved femtosecond stimulated Raman spectroscopy (FSRS) is used to explore the ultrafast intersystem crossing between the metal-to-ligand charge-transfer (MLCT) states of tris(2,2'-bipyridine)ruthenium(II) (). Excitation at 480?nm by a ~35?fs actinic pump pulse initiates electron transfe...
| Autors principals: | , , , |
|---|---|
| Format: | Journal article |
| Idioma: | English |
| Publicat: |
2006
|