Spin relaxation effects in photochemically induced dynamic nuclear polarization spectroscopy of nuclei with strongly anisotropic hyperfine couplings.
We describe experimental results and theoretical models for nuclear and electron spin relaxation processes occurring during the evolution of 19F-labeled geminate radical pairs on a nanosecond time scale. In magnetic fields of over 10 T, electron-nucleus dipolar cross-relaxation and longitudinal Delt...
| Main Authors: | , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
American Chemical Society
2007
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| Subjects: |