Rationalization of interactions in precious metal/ceria catalysts using the d-band center model.

A correlation between ceria reducibility and the precious-metal d-band center is reported for ceria-supported precious-metal catalysts. The results could provide the missing link to fully explain the occurrence of strong metal-support interaction (SMSI) and hydrogen spillover in catalysts that consi...

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Detalhes bibliográficos
Main Authors: Acerbi, N, Tsang, S, Jones, G, Golunski, S, Collier, P
Formato: Journal article
Idioma:English
Publicado em: 2013