Synthesis and Reactions of a Cyclopentadienyl-Amidinate Titanium tert-Butoxyimido Compound
We report the first detailed reactivity study of a group 4 alkoxyimido complex, namely CpTi{PhC(NiPr)2}(NOtBu) (19), with heterocumulenes, aldehydes, ketones, organic nitriles, ArF5CCH, and B(ArF5)3 (ArF5 = C6F 5). Compound 19 was synthesized via imide/alkoxyamine exchange from CpTi{PhC(NiPr)2}(NtBu...
| Main Authors: | , , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
American Chemical Society
2013
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