THE ALPHA-VINYLATION OF BETA-DICARBONYL COMPOUNDS BY ALK-1-ENYL-LEAD TRIACETATES

Treatment of (E,E)-distyrylmercury (1) with lead tetra-acetate gave a mixture of (E)-styrylmercury acetate (3) and (E)-styryl-lead triacetate (2), which decomposed to (E)-styryl acetate (4) and lead(II) acetate. The vinyl-lead compound (2), generated in this way, reacted rapidly with β-keto ester (5...

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Detalhes bibliográficos
Main Authors: Moloney, M, Pinhey, J
Formato: Journal article
Idioma:English
Publicado em: 1988