Metal free fluoroamination of allylsilanes: A route to 3-fluoropyrrolidines

The intramolecular fluoroamination of homoallylic amines activated by a triisopropylsilyl or p-tolyldiisopropylsilyl group was successfully performed in the presence of Selectfluor® in acetonitrile leading to anti or syn 3-fluoropyrrolidines. The stereochemical outcome of these fluorocyclizations is...

Full description

Bibliographic Details
Main Authors: Combettes, L, Lozano, O, Gouverneur, V
Format: Journal article
Language:English
Published: 2012