Metal free fluoroamination of allylsilanes: A route to 3-fluoropyrrolidines

The intramolecular fluoroamination of homoallylic amines activated by a triisopropylsilyl or p-tolyldiisopropylsilyl group was successfully performed in the presence of Selectfluor® in acetonitrile leading to anti or syn 3-fluoropyrrolidines. The stereochemical outcome of these fluorocyclizations is...

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Detalles Bibliográficos
Main Authors: Combettes, L, Lozano, O, Gouverneur, V
Formato: Journal article
Idioma:English
Publicado: 2012