C-Cl activation of the weakly coordinating anion [B(3,5-Cl2C6H3)4]- at a Rh(I) centre in solution and the solid-state.
Addition of H2 to [Rh((i)Bu2PCH2CH2P(i)Bu2)(NBD)][BAr(Cl)4] (NBD = norbornadiene, Ar(Cl) = 3,5-Cl2C6H3) in the solid-state results in the rapid formation of zwitterionic [Rh((i)Bu2PCH2CH2P(i)Bu2){(η(6)-C6H3Cl2)BAr(Cl)3}] by a gas/solid reaction. This undergoes slow C-Cl bond cleavage in the solid-st...
| Main Authors: | , |
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| Format: | Journal article |
| Language: | English |
| Published: |
2013
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