C-Cl activation of the weakly coordinating anion [B(3,5-Cl2C6H3)4]- at a Rh(I) centre in solution and the solid-state.
Addition of H2 to [Rh((i)Bu2PCH2CH2P(i)Bu2)(NBD)][BAr(Cl)4] (NBD = norbornadiene, Ar(Cl) = 3,5-Cl2C6H3) in the solid-state results in the rapid formation of zwitterionic [Rh((i)Bu2PCH2CH2P(i)Bu2){(η(6)-C6H3Cl2)BAr(Cl)3}] by a gas/solid reaction. This undergoes slow C-Cl bond cleavage in the solid-st...
| Main Authors: | , |
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| Format: | Journal article |
| Language: | English |
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2013
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| _version_ | 1826261900175867904 |
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| author | Pike, S Weller, A |
| author_facet | Pike, S Weller, A |
| author_sort | Pike, S |
| collection | OXFORD |
| description | Addition of H2 to [Rh((i)Bu2PCH2CH2P(i)Bu2)(NBD)][BAr(Cl)4] (NBD = norbornadiene, Ar(Cl) = 3,5-Cl2C6H3) in the solid-state results in the rapid formation of zwitterionic [Rh((i)Bu2PCH2CH2P(i)Bu2){(η(6)-C6H3Cl2)BAr(Cl)3}] by a gas/solid reaction. This undergoes slow C-Cl bond cleavage in the solid-state to ultimately afford the dimeric Rh(III) complex [RhCl((i)Bu2PCH2CH2P(i)Bu2){C6H3Cl(BAr(Cl)3)}]2. This reactivity is mirrored in solution (CH2Cl2). Kinetic data for the C-Cl activation in both the solid-state and solution are reported. |
| first_indexed | 2024-03-06T19:27:51Z |
| format | Journal article |
| id | oxford-uuid:1c6491f8-3117-4189-b571-7a601b2de16d |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-06T19:27:51Z |
| publishDate | 2013 |
| record_format | dspace |
| spelling | oxford-uuid:1c6491f8-3117-4189-b571-7a601b2de16d2022-03-26T11:05:27ZC-Cl activation of the weakly coordinating anion [B(3,5-Cl2C6H3)4]- at a Rh(I) centre in solution and the solid-state.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:1c6491f8-3117-4189-b571-7a601b2de16dEnglishSymplectic Elements at Oxford2013Pike, SWeller, AAddition of H2 to [Rh((i)Bu2PCH2CH2P(i)Bu2)(NBD)][BAr(Cl)4] (NBD = norbornadiene, Ar(Cl) = 3,5-Cl2C6H3) in the solid-state results in the rapid formation of zwitterionic [Rh((i)Bu2PCH2CH2P(i)Bu2){(η(6)-C6H3Cl2)BAr(Cl)3}] by a gas/solid reaction. This undergoes slow C-Cl bond cleavage in the solid-state to ultimately afford the dimeric Rh(III) complex [RhCl((i)Bu2PCH2CH2P(i)Bu2){C6H3Cl(BAr(Cl)3)}]2. This reactivity is mirrored in solution (CH2Cl2). Kinetic data for the C-Cl activation in both the solid-state and solution are reported. |
| spellingShingle | Pike, S Weller, A C-Cl activation of the weakly coordinating anion [B(3,5-Cl2C6H3)4]- at a Rh(I) centre in solution and the solid-state. |
| title | C-Cl activation of the weakly coordinating anion [B(3,5-Cl2C6H3)4]- at a Rh(I) centre in solution and the solid-state. |
| title_full | C-Cl activation of the weakly coordinating anion [B(3,5-Cl2C6H3)4]- at a Rh(I) centre in solution and the solid-state. |
| title_fullStr | C-Cl activation of the weakly coordinating anion [B(3,5-Cl2C6H3)4]- at a Rh(I) centre in solution and the solid-state. |
| title_full_unstemmed | C-Cl activation of the weakly coordinating anion [B(3,5-Cl2C6H3)4]- at a Rh(I) centre in solution and the solid-state. |
| title_short | C-Cl activation of the weakly coordinating anion [B(3,5-Cl2C6H3)4]- at a Rh(I) centre in solution and the solid-state. |
| title_sort | c cl activation of the weakly coordinating anion b 3 5 cl2c6h3 4 at a rh i centre in solution and the solid state |
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