ALK-1-YNYLLEAD TRIACETATES AS ALK-1-YNYL CARBOCATION EQUIVALENTS - THE ALPHA-ALK-1-YNYLATION OF BETA-DICARBONYL COMPOUNDS AND NITRONATE SALTS

The addition of lead tetraacetate to a chloroform solution of alk-l-ynyltrimethylstannane results in the rapid formation of trimethylstannyl acetate and an unstable species, believed to be the corresponding alk-l-ynyllead triacetate, which can effect the rapid α-alkynylation of β-dicarbonyl compound...

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Bibliographic Details
Main Authors: Moloney, M, Pinhey, J, Roche, E
Format: Journal article
Language:English
Published: 1986