Bifunctional iminophosphorane catalyzed enantioselective ketimine phospha-Mannich reaction

The enantioselective phospha-Mannich reaction of diethyl phosphite to unactivated N-DPP-protected ketimines catalyzed by a bifunctional iminophosphorane (BIMP) superbase organocatalyst is described. The reaction is applicable to ketimines bearing electron-rich and electron-poor aryl substituents and...

Бүрэн тодорхойлолт

Номзүйн дэлгэрэнгүй
Үндсэн зохиолчид: Robertson, G, Farley, A, Dixon, D
Формат: Journal article
Хэвлэсэн: Thieme Publishing 2015