Catalyst selection facilitates the use of heterocyclic sulfinates as general nucleophilic coupling partners in palladium-catalyzed coupling reactions

A range of 5- and 6-membered heterocycle-derived sulfinates are shown to be effective nucleophilic coupling partners with aryl chlorides and bromides using Pd(0) catalysis. The use of optimal reaction conditions, specifically incorporating a P(tBu)2Me-derived Pd catalyst, allowed reactions to be per...

Ausführliche Beschreibung

Bibliographische Detailangaben
Hauptverfasser: Markovic, T, Rocke, B, Blakemore, D, Mascitti, V, Willis, M
Format: Journal article
Veröffentlicht: American Chemical Society 2017