Planar diffusion to macro disc electrodes-what electrode size is required for the Cottrell and Randles-Sevcik equations to apply quantitatively?

Simulations and experiments are reported which investigate the size of a macro disc electrode necessary to quantitatively show the chronoamperometric or voltammetric behaviour predicted by the Cottrell equation or the Randles-Sevcik equation on the basis of exclusive one-dimensional diffusional mass...

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Bibliographic Details
Main Authors: Ngamchuea, K, Eloul, S, Tschulik, K, Compton, R
Format: Journal article
Language:English
Published: Springer New York LLC 2014