Mechanistic studies on a Cu-catalyzed asymmetric allylic al-kylation with cyclic racemic starting materials

Mechanistic studies on a Cu-catalyzed asymmetric allylic al-kylation with cyclic racemic starting materials

Mechanistic studies on Cu-catalysed asymmetric additions of alkylzirconocene nucleophiles to racemic allylic halide electrophiles were conducted using a combination of isotopic labelling, NMR spectroscopy, kinetic modeling, structure-activity relationships and new reaction development. Kinetic and d...

पूर्ण विवरण

ग्रंथसूची विवरण
मुख्य लेखकों:	Rideau, E, You, H, Sidera, M, Claridge, T, Fletcher, S
स्वरूप:	Journal article
प्रकाशित:	American Chemical Society 2017

समान संसाधन

Cu-catalyzed asymmetric addition of sp²-hybridized zirconium nucleophiles to racemic allyl bromides.
द्वारा: Sidera, M, और अन्य
प्रकाशित: (2015)

Cu-catalyzed asymmetric addition of sp2-hybridized zirconium nucleophiles to racemic allyl bromides
द्वारा: Sidera, M, और अन्य
प्रकाशित: (2015)

Rhodium-catalysed asymmetric allylic arylation of racemic halides with arylboronic acids
द्वारा: Sidera, M, और अन्य
प्रकाशित: (2015)

Non-stabilized nucleophiles in Cu-catalysed dynamic kinetic asymmetric allylic alkylation
द्वारा: You, H, और अन्य
प्रकाशित: (2015)

Asymmetric cross-coupling of alkyl, alkenyl and (hetero)aryl nucleophiles with racemic allyl halides
द्वारा: Schafer, P, और अन्य
प्रकाशित: (2017)

Asymmetric Suzuki-Miyaura coupling of heterocycles via Rhodium-catalysed allylic arylation of racemates
द्वारा: Schäfer, P, और अन्य
प्रकाशित: (2017)

Copper-catalysed asymmetric allylic alkylation of alkylzirconocenes to racemic 3,6-dihydro-2H-pyrans
द्वारा: Emeline Rideau, और अन्य
प्रकाशित: (2015-12-01)

Correction: Author Correction: Asymmetric Suzuki-Miyaura coupling of heterocycles via Rhodium-catalysed allylic arylation of racemates
द्वारा: Philipp Schäfer, और अन्य
प्रकाशित: (2018-05-01)

Highly enantioselective hiyama cross-coupling via Rh-catalyzed allylic arylation of racemic allyl chlorides
द्वारा: Fletcher, S
प्रकाशित: (2019)

Nickel-Catalyzed Asymmetric Negishi Cross-Couplings of Racemic Secondary Allylic Chlorides with Alkylzincs
द्वारा: Lou, Sha, और अन्य
प्रकाशित: (2011)

Highly enantioselective rhodium-catalyzed cross-coupling of boronic acids and racemic allyl halides
द्वारा: González, J, और अन्य
प्रकाशित: (2019)

Kivikauden kylät Keski-Pohjanmaalla
द्वारा: Lauri Skantsi
प्रकाशित: (2023-06-01)

Copper catalyzed asymmetric synthesis of chiral allylic esters.
द्वारा: Geurts, K, और अन्य
प्रकाशित: (2006)

Copper-catalyzed asymmetric conjugate addition of alkylzirconium reagents to cyclic enones to form quaternary centers.
द्वारा: Roth, P, और अन्य
प्रकाशित: (2014)

Mechanistic investigation of Rh(i)-catalysedasymmetric Suzuki–Miyaura coupling withracemic allyl halides
द्वारा: Van Dijk, LL, और अन्य
प्रकाशित: (2021)

The Copper-Catalyzed Asymmetric Allylic Substitution
द्वारा: Alexandre Alexakis, और अन्य
प्रकाशित: (2006-03-01)

Asymmetric synthesis of nortropanes via Rh-catalyzed allylic arylation
द्वारा: Zhang, Y, और अन्य
प्रकाशित: (2022)

Desymmetrization of meso-bisphosphates via rhodium catalyzed asymmetric allylic arylation
द्वारा: Jacques, R, और अन्य
प्रकाशित: (2019)

Copper-catalyzed asymmetric allylic substitution reactions with organozinc and Grignard reagents
द्वारा: Geurts, K, और अन्य
प्रकाशित: (2008)

Organozirconocene nucleophiles in Cu-catalysed asymmetric transformations: methodologies, applications to total synthesis and NMR mechanistic studies
द्वारा: Rideau, E
प्रकाशित: (2016)

Palladium Catalyzed Allylic C-H Alkylation: A Mechanistic Perspective
द्वारा: Casper Junker Engelin, और अन्य
प्रकाशित: (2011-01-01)

Asymmetric allylic alkynylation catalyzed by guanidine copper(I) complex
द्वारा: Cui, Xiyang
प्रकाशित: (2018)

Copper(I)/guanidine catalyzed asymmetric allylic borylation reaction
द्वारा: Ge, Yicen
प्रकाशित: (2018)

Chalcogen-containing oxazolines in the palladium-catalyzed asymmetric allylic alkylation
द्वारा: Braga Antonio L., और अन्य
प्रकाशित: (2006-01-01)

Copper(I)-catalyzed asymmetric 1,6-conjugate allylation
द्वारा: Chang-Yun Shi, और अन्य
प्रकाशित: (2020-10-01)

Formation of quaternary centers by copper-catalyzed asymmetric conjugate addition of alkylzirconium reagents.
द्वारा: Sidera, M, और अन्य
प्रकाशित: (2013)

Additions to racemates: a strategy for developing asymmetric cross-coupling reactions
द्वारा: Goetzke, F, और अन्य
प्रकाशित: (2021)

Rh‐Catalyzed Hydroamination of Allenes: Asymmetric N‐Allylation of Amino Acids and Peptides
द्वारा: Edward Damer, और अन्य
प्रकाशित: (2024-09-01)

Palladium-catalyzed asymmetric allylic 4-pyridinylation via electroreductive substitution reaction
द्वारा: Weijie Ding, और अन्य
प्रकाशित: (2022-09-01)

Nickel-catalyzed asymmetric cross-couplings of secondary allylic chlorides and planar-chiral compounds in asymmetric synthesis
द्वारा: Son, Sunghee
प्रकाशित: (2009)

Palladium-catalyzed allylic alkylation of enamides and allylic acetates
द्वारा: Lim, Juan Mei
प्रकाशित: (2012)

Mechanistic Studies Lead to Dramatically Improved Reaction Conditions for the Cu-Catalyzed Asymmetric Hydroamination of Olefins
द्वारा: Bandar, Jeffrey, और अन्य
प्रकाशित: (2017)

Solvent effect in lipase-catalyzed racemate resolution/
द्वारा: 241971 Anthonsen, Thorleif, और अन्य

Regiodivergent and Diastereoselective CuH-Catalyzed Allylation of Imines with Terminal Allenes
द्वारा: Liu, Richard Y., और अन्य
प्रकाशित: (2018)

Guanidine-copper complex catalyzed allylic borylation for the enantioconvergent synthesis of tertiary cyclic allylboronates
द्वारा: Ge, Yicen, और अन्य
प्रकाशित: (2021)

Organophotoredox-catalyzed intermolecular formal Grob fragmentation of cyclic alcohols with activated allylic acetates
द्वारा: Zeng, Wubing, और अन्य
प्रकाशित: (2023)

Non-stabilized nucleophiles in cu-catalyzed asymmetric synthesis
द्वारा: You, H
प्रकाशित: (2016)

Pd-Catalyzed Asymmetric Allylic Substitution Cascade via Desymmetrization for the Construction of Chiral Polyheterocycles
द्वारा: Xuezhen Kou, और अन्य
प्रकाशित: (2024-09-01)

Palladium catalyzed allylic fluorination
द्वारा: Hollingworth, C, और अन्य
प्रकाशित: (2012)

Palladium-catalyzed allylic fluorination.
द्वारा: Hollingworth, C, और अन्य
प्रकाशित: (2011)