Mechanistic studies on a Cu-catalyzed asymmetric allylic al-kylation with cyclic racemic starting materials

Mechanistic studies on a Cu-catalyzed asymmetric allylic al-kylation with cyclic racemic starting materials

Mechanistic studies on Cu-catalysed asymmetric additions of alkylzirconocene nucleophiles to racemic allylic halide electrophiles were conducted using a combination of isotopic labelling, NMR spectroscopy, kinetic modeling, structure-activity relationships and new reaction development. Kinetic and d...

Бүрэн тодорхойлолт

Номзүйн дэлгэрэнгүй
Үндсэн зохиолчид:	Rideau, E, You, H, Sidera, M, Claridge, T, Fletcher, S
Формат:	Journal article
Хэвлэсэн:	American Chemical Society 2017

Ижил төстэй зүйлс

Cu-catalyzed asymmetric addition of sp²-hybridized zirconium nucleophiles to racemic allyl bromides.
-н: Sidera, M, зэрэг
Хэвлэсэн: (2015)

Cu-catalyzed asymmetric addition of sp2-hybridized zirconium nucleophiles to racemic allyl bromides
-н: Sidera, M, зэрэг
Хэвлэсэн: (2015)

Rhodium-catalysed asymmetric allylic arylation of racemic halides with arylboronic acids
-н: Sidera, M, зэрэг
Хэвлэсэн: (2015)

Non-stabilized nucleophiles in Cu-catalysed dynamic kinetic asymmetric allylic alkylation
-н: You, H, зэрэг
Хэвлэсэн: (2015)

Asymmetric cross-coupling of alkyl, alkenyl and (hetero)aryl nucleophiles with racemic allyl halides
-н: Schafer, P, зэрэг
Хэвлэсэн: (2017)

Asymmetric Suzuki-Miyaura coupling of heterocycles via Rhodium-catalysed allylic arylation of racemates
-н: Schäfer, P, зэрэг
Хэвлэсэн: (2017)

Copper-catalysed asymmetric allylic alkylation of alkylzirconocenes to racemic 3,6-dihydro-2H-pyrans
-н: Emeline Rideau, зэрэг
Хэвлэсэн: (2015-12-01)

Correction: Author Correction: Asymmetric Suzuki-Miyaura coupling of heterocycles via Rhodium-catalysed allylic arylation of racemates
-н: Philipp Schäfer, зэрэг
Хэвлэсэн: (2018-05-01)

Highly enantioselective hiyama cross-coupling via Rh-catalyzed allylic arylation of racemic allyl chlorides
-н: Fletcher, S
Хэвлэсэн: (2019)

Nickel-Catalyzed Asymmetric Negishi Cross-Couplings of Racemic Secondary Allylic Chlorides with Alkylzincs
-н: Lou, Sha, зэрэг
Хэвлэсэн: (2011)

Highly enantioselective rhodium-catalyzed cross-coupling of boronic acids and racemic allyl halides
-н: González, J, зэрэг
Хэвлэсэн: (2019)

Kivikauden kylät Keski-Pohjanmaalla
-н: Lauri Skantsi
Хэвлэсэн: (2023-06-01)

Copper catalyzed asymmetric synthesis of chiral allylic esters.
-н: Geurts, K, зэрэг
Хэвлэсэн: (2006)

Copper-catalyzed asymmetric conjugate addition of alkylzirconium reagents to cyclic enones to form quaternary centers.
-н: Roth, P, зэрэг
Хэвлэсэн: (2014)

Mechanistic investigation of Rh(i)-catalysedasymmetric Suzuki–Miyaura coupling withracemic allyl halides
-н: Van Dijk, LL, зэрэг
Хэвлэсэн: (2021)

The Copper-Catalyzed Asymmetric Allylic Substitution
-н: Alexandre Alexakis, зэрэг
Хэвлэсэн: (2006-03-01)

Asymmetric synthesis of nortropanes via Rh-catalyzed allylic arylation
-н: Zhang, Y, зэрэг
Хэвлэсэн: (2022)

Desymmetrization of meso-bisphosphates via rhodium catalyzed asymmetric allylic arylation
-н: Jacques, R, зэрэг
Хэвлэсэн: (2019)

Copper-catalyzed asymmetric allylic substitution reactions with organozinc and Grignard reagents
-н: Geurts, K, зэрэг
Хэвлэсэн: (2008)

Organozirconocene nucleophiles in Cu-catalysed asymmetric transformations: methodologies, applications to total synthesis and NMR mechanistic studies
-н: Rideau, E
Хэвлэсэн: (2016)

Palladium Catalyzed Allylic C-H Alkylation: A Mechanistic Perspective
-н: Casper Junker Engelin, зэрэг
Хэвлэсэн: (2011-01-01)

Asymmetric allylic alkynylation catalyzed by guanidine copper(I) complex
-н: Cui, Xiyang
Хэвлэсэн: (2018)

Copper(I)/guanidine catalyzed asymmetric allylic borylation reaction
-н: Ge, Yicen
Хэвлэсэн: (2018)

Chalcogen-containing oxazolines in the palladium-catalyzed asymmetric allylic alkylation
-н: Braga Antonio L., зэрэг
Хэвлэсэн: (2006-01-01)

Copper(I)-catalyzed asymmetric 1,6-conjugate allylation
-н: Chang-Yun Shi, зэрэг
Хэвлэсэн: (2020-10-01)

Formation of quaternary centers by copper-catalyzed asymmetric conjugate addition of alkylzirconium reagents.
-н: Sidera, M, зэрэг
Хэвлэсэн: (2013)

Additions to racemates: a strategy for developing asymmetric cross-coupling reactions
-н: Goetzke, F, зэрэг
Хэвлэсэн: (2021)

Rh‐Catalyzed Hydroamination of Allenes: Asymmetric N‐Allylation of Amino Acids and Peptides
-н: Edward Damer, зэрэг
Хэвлэсэн: (2024-09-01)

Palladium-catalyzed asymmetric allylic 4-pyridinylation via electroreductive substitution reaction
-н: Weijie Ding, зэрэг
Хэвлэсэн: (2022-09-01)

Nickel-catalyzed asymmetric cross-couplings of secondary allylic chlorides and planar-chiral compounds in asymmetric synthesis
-н: Son, Sunghee
Хэвлэсэн: (2009)

Palladium-catalyzed allylic alkylation of enamides and allylic acetates
-н: Lim, Juan Mei
Хэвлэсэн: (2012)

Mechanistic Studies Lead to Dramatically Improved Reaction Conditions for the Cu-Catalyzed Asymmetric Hydroamination of Olefins
-н: Bandar, Jeffrey, зэрэг
Хэвлэсэн: (2017)

Solvent effect in lipase-catalyzed racemate resolution/
-н: 241971 Anthonsen, Thorleif, зэрэг

Regiodivergent and Diastereoselective CuH-Catalyzed Allylation of Imines with Terminal Allenes
-н: Liu, Richard Y., зэрэг
Хэвлэсэн: (2018)

Guanidine-copper complex catalyzed allylic borylation for the enantioconvergent synthesis of tertiary cyclic allylboronates
-н: Ge, Yicen, зэрэг
Хэвлэсэн: (2021)

Organophotoredox-catalyzed intermolecular formal Grob fragmentation of cyclic alcohols with activated allylic acetates
-н: Zeng, Wubing, зэрэг
Хэвлэсэн: (2023)

Non-stabilized nucleophiles in cu-catalyzed asymmetric synthesis
-н: You, H
Хэвлэсэн: (2016)

Pd-Catalyzed Asymmetric Allylic Substitution Cascade via Desymmetrization for the Construction of Chiral Polyheterocycles
-н: Xuezhen Kou, зэрэг
Хэвлэсэн: (2024-09-01)

Palladium catalyzed allylic fluorination
-н: Hollingworth, C, зэрэг
Хэвлэсэн: (2012)

Palladium-catalyzed allylic fluorination.
-н: Hollingworth, C, зэрэг
Хэвлэсэн: (2011)