Diastereoselective anomeric oxygen to carbon rearrangements of silyl enol ether derivatives of lactols.

Lewis acid promoted oxygen to carbon rearrangement of anomerically linked silyl enol ethers gives a new and diastereoselective route to the corresponding 2-α-hydroxyketone substituted products.

Bibliografische gegevens
Hoofdauteurs: Dixon, D, Ley, S, Tate, E
Formaat: Journal article
Taal:English
Gepubliceerd in: 1998
Omschrijving
Samenvatting:Lewis acid promoted oxygen to carbon rearrangement of anomerically linked silyl enol ethers gives a new and diastereoselective route to the corresponding 2-α-hydroxyketone substituted products.