Diastereoselective anomeric oxygen to carbon rearrangements of silyl enol ether derivatives of lactols.

Lewis acid promoted oxygen to carbon rearrangement of anomerically linked silyl enol ethers gives a new and diastereoselective route to the corresponding 2-α-hydroxyketone substituted products.

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Autori principali: Dixon, D, Ley, S, Tate, E
Natura: Journal article
Lingua:English
Pubblicazione: 1998