Carbon monoxide activation by a molecular aluminium imide: C-O bond cleavage and C-C bond formation

Anionic molecular imide complexes of aluminium are accessible via a rational synthetic approach involving the reactions of organo azides with a potassium aluminyl reagent. In the case of K2 [(NON)Al(NDipp)]2 (NON=4,5-bis(2,6-diisopropylanilido)-2,7-di-tert-butyl-9,9-dimethyl-xanthene; Dipp=2,6-diiso...

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Bibliographic Details
Main Authors: Heilmann, A, Hicks, J, Vasko, P, Goicoechea, JM, Aldridge, S
Format: Journal article
Language:English
Published: Wiley 2020