Synthesis and reactions of β-diketiminate-supported complexes with Mg-Fe or Yb-Fe bonds.
Reaction of [M(NacNac)I(THF)]n (M = Mg, Ca or Yb; n = 1 or 2) with KFp gave Mg(NacNac)Fp(THF) (, Mg-Fe = 2.6326(4) Å) or [M(NacNac)(μ-Fp)(THF)]2 (M = Ca or Yb (10), no M-Fe bonds); reaction of with [YbFp2(THF)3]2 gave [{Yb(NacNac)(THF)}2(μ-YbFp4)] (Yb-Fe = 2.9758(5)-3.1702(5) Å) containing the first...
| Main Authors: | , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
2013
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