Synthesis and reactions of β-diketiminate-supported complexes with Mg-Fe or Yb-Fe bonds.
Reaction of [M(NacNac)I(THF)]n (M = Mg, Ca or Yb; n = 1 or 2) with KFp gave Mg(NacNac)Fp(THF) (, Mg-Fe = 2.6326(4) Å) or [M(NacNac)(μ-Fp)(THF)]2 (M = Ca or Yb (10), no M-Fe bonds); reaction of with [YbFp2(THF)3]2 gave [{Yb(NacNac)(THF)}2(μ-YbFp4)] (Yb-Fe = 2.9758(5)-3.1702(5) Å) containing the first...
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| Format: | Journal article |
| Language: | English |
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2013
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| _version_ | 1797058266789838848 |
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| author | Blake, M Kaltsoyannis, N Mountford, P |
| author_facet | Blake, M Kaltsoyannis, N Mountford, P |
| author_sort | Blake, M |
| collection | OXFORD |
| description | Reaction of [M(NacNac)I(THF)]n (M = Mg, Ca or Yb; n = 1 or 2) with KFp gave Mg(NacNac)Fp(THF) (, Mg-Fe = 2.6326(4) Å) or [M(NacNac)(μ-Fp)(THF)]2 (M = Ca or Yb (10), no M-Fe bonds); reaction of with [YbFp2(THF)3]2 gave [{Yb(NacNac)(THF)}2(μ-YbFp4)] (Yb-Fe = 2.9758(5)-3.1702(5) Å) containing the first example of a lanthanide bound solely to four transition metals; reaction of with TolNCNTol gave Mg(NacNac){(NTol)2CFp} via the first net insertion of an unsaturated substrate into an alkaline earth-transition metal bond (NacNac = HC{C(Me)N(2,6-C6H3(i)Pr2)}2; Fp = CpFe(CO)2; Tol = 4-C6H4Me). |
| first_indexed | 2024-03-06T19:48:02Z |
| format | Journal article |
| id | oxford-uuid:2301f90e-0032-4f64-b72f-9e6aff08f0f1 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-06T19:48:02Z |
| publishDate | 2013 |
| record_format | dspace |
| spelling | oxford-uuid:2301f90e-0032-4f64-b72f-9e6aff08f0f12022-03-26T11:41:53ZSynthesis and reactions of β-diketiminate-supported complexes with Mg-Fe or Yb-Fe bonds.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:2301f90e-0032-4f64-b72f-9e6aff08f0f1EnglishSymplectic Elements at Oxford2013Blake, MKaltsoyannis, NMountford, PReaction of [M(NacNac)I(THF)]n (M = Mg, Ca or Yb; n = 1 or 2) with KFp gave Mg(NacNac)Fp(THF) (, Mg-Fe = 2.6326(4) Å) or [M(NacNac)(μ-Fp)(THF)]2 (M = Ca or Yb (10), no M-Fe bonds); reaction of with [YbFp2(THF)3]2 gave [{Yb(NacNac)(THF)}2(μ-YbFp4)] (Yb-Fe = 2.9758(5)-3.1702(5) Å) containing the first example of a lanthanide bound solely to four transition metals; reaction of with TolNCNTol gave Mg(NacNac){(NTol)2CFp} via the first net insertion of an unsaturated substrate into an alkaline earth-transition metal bond (NacNac = HC{C(Me)N(2,6-C6H3(i)Pr2)}2; Fp = CpFe(CO)2; Tol = 4-C6H4Me). |
| spellingShingle | Blake, M Kaltsoyannis, N Mountford, P Synthesis and reactions of β-diketiminate-supported complexes with Mg-Fe or Yb-Fe bonds. |
| title | Synthesis and reactions of β-diketiminate-supported complexes with Mg-Fe or Yb-Fe bonds. |
| title_full | Synthesis and reactions of β-diketiminate-supported complexes with Mg-Fe or Yb-Fe bonds. |
| title_fullStr | Synthesis and reactions of β-diketiminate-supported complexes with Mg-Fe or Yb-Fe bonds. |
| title_full_unstemmed | Synthesis and reactions of β-diketiminate-supported complexes with Mg-Fe or Yb-Fe bonds. |
| title_short | Synthesis and reactions of β-diketiminate-supported complexes with Mg-Fe or Yb-Fe bonds. |
| title_sort | synthesis and reactions of β diketiminate supported complexes with mg fe or yb fe bonds |
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