Ag-catalyzed stereoselective aminosulfonylation of alkynes

A silver-catalyzed intermolecular aminosulfonylation of terminal alkynes with sodium sulfinates and TMSN3 is reported. This three component reaction proceeds through sequential hydroazidation of the terminal alkyne, and addition of a sulfonyl radical to the resultant vinyl azide. The method enables...

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Bibliographic Details
Main Authors: Ning, Y, Ji, Q, Liao, P, Anderson, E, Bi, X
Format: Journal article
Published: Wiley 2017