Extending conjugation in porphyrin dimer carbocations.
The addition of alkynyl porphyrins to carbonyl compounds was used to prepare a series of porphyrin dimer tertiary alcohols. Treatment of these alcohols with acid gave conjugated carbocations with three to nine carbon atoms bridging between the porphyrins. All these carbocations show strong absorptio...
| Main Authors: | , |
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| Format: | Journal article |
| Language: | English |
| Published: |
2010
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