Template-directed synthesis of pi-conjugated porphyrin [2]rotaxanes and a [4]catenane based on a six-porphyrin nanoring

[2]Rotaxanes consisting of butadiyne-linked porphyrin dimers threaded through a phenanthroline-containing macrocycle, can be synthesised by an active-metal template directed copper-mediated Glaser coupling, in yields of up to 61%, without requiring a large excess of the macrocycle. The crystal struc...

Полное описание

Библиографические подробности
Главные авторы: Langton, M, Matichak, J, Thompson, A, Anderson, H
Формат: Journal article
Язык:English
Опубликовано: 2011