Understanding the origins of remote asymmetric induction in the boron aldol reactions of beta-alkoxy methyl ketones.
We report theoretical studies into the remote 1,5-stereoinduction shown by certain types of beta-alkoxy methyl ketones in boron-mediated aldol reactions with achiral aldehydes. For a range of common alkoxy groups, our calculations are in excellent agreement with experimentally observed diastereosele...
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| Egile Nagusiak: |
Paton, R,
Goodman, J |
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| Formatua: | Journal article
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| Hizkuntza: | English |
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| Argitaratua: |
2006
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