Synthesis of new bulky bis(pyrazolyl)methane carboxylate (heteroscorpionate) ligands and their complexes with iron, manganese and nickel.

Three new sterically demanding ligands based on the bispyrazolylacetic acid motif have been prepared and complexes with Fe(II), Fe(III), Ni(II) and Mn(II) have been synthesised and characterised. Single crystal X-ray structures are included for two of the ligands in the protonated form and ten other...

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Bibliographic Details
Main Authors: Jones, M, Baldwin, J, Cowley, A, Dilworth, JR, Karpov, A, Smiljanic, N, Thompson, A, Adlington, R
Format: Journal article
Language:English
Published: 2012