Oxygen to carbon rearrangements of anomerically linked alkenols from tetrahydropyran derivatives: an investigation of the reaction mechanism via a double isotopic labelling crossover study

A variety of alkenol tetrahydropyran derivatives were prepared and subjected to a tin tetrachloride promoted anomeric oxygen to carbon rearrangement. Using this methodology many of the corresponding carbon-linked structures were synthesised, including alkenes and bicyclic ethers, in good yields. On...

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Príomhchruthaitheoirí: Buffet, M, Dixon, D, Edwards, G, Ley, S, Tate, E
Formáid: Journal article
Teanga:English
Foilsithe / Cruthaithe: 2000