Mono- and bi-nuclear titanium imido complexes supported by aryloxide ligands: fine control by ortho substituents

Reaction of the titanium imido complexes [Ti(NR)Cl2(py)3] (R = But, C6H3Me2-2,6 or C6H3Pri2-2,6; py = pyridine) with 2 equivalents of lithium aryloxide Li[OC6H3R′2-2,6] (R′ = Me, Pri or But) afforded the mononuclear four-or five-co-ordinate or binuclear four-co-ordinate complexes [{Ti(NR)(OC6H3R′2-2...

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Main Authors: Collier, P, Blake, A, Mountford, P
格式: Journal article
语言:English
出版: 1997