Structure and dynamics of a dihydrogen/hydride ansa molybdenocene complex.
In contrast to [Cp(2)MoH(3)](+), which is a thermally stable trihydride complex, the ansa-bridged analogue [(eta-C(5)H(4))(2)CMe(2)MoH(H(2))](+) (1) is a thermally labile dihydrogen/hydride complex. Partial deuteration of the hydride ligands allows observation of J(H)(-)(D) = 11.9 Hz in 1-d(1) and 9...
| Main Authors: | , , , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
2004
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